Product ID:HOT MELT GLASS PREPREG. R1604
MSDS Date:01/01/1987
FSC:8040
NIIN:00F006919
MSDS Number: BBWTV

CIBA-GEIGY CORP REN PLASTICS DIV

4917 DAWN AVE
EAST LANSING, MI 48823-5605
US

Emergency Phone: 517-351-5900

Info Phone: 517-351-5900 / FAX 517-351-9003

Cage: 02684

CIBA SPECIALTY CHEMICALS CORPORATION

EAST LANSING, MI 48823-5691 US

Telephone: 517-351-5900

Cage: 02684

GLYCIDYL BENZENAMINE

4,4'-METHYLENE DIANILINE (SARA III)

CAS: 101-77-9

RTECS: BY5425000

ACGIH TLV: S; 0.1 PPM; A2; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:NOT GIVEN
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:TOXIC BY INHALATION AND SKIN CONTACT.
SUSPECTED HUMAN CARCINOGEN. MAY CAUSE EYE IRRITATION, SKIN
IRRITATION, RESPIRATORY TRACT IRRITATION.
Explanation of Carcinogenicity:PRODUCT CONTAINS MDA (101-77-9) WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:FEVER, CHILLS, ANOREXIA, VOMITING. MAY CAUSE
TRANSIENT LIVER DAMAGE AND CYANOSIS, EYE IRRITATION, SKIN
IRRITATION, RASHES, RESPIRATORY TRACT IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH
WITH SOAP & WATER. REMOVE WITH RESIN CREAM. DON'T USE SOLVENTS.
REMOVE/WASH CONTAMINATED CLOTHING PRIOR TO REUSE. INHALATION:
REMOVE TO FRESH AIR. INGESTION: GIVE LARGE QTYS OF WATER. GET
MEDICAL ATTENTION.

Flash Point:NONFLAMMABLE
Extinguishing Media:CO2, FOAM, DRY CHEMICAL, WATER SPRAY
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND
FULL FACE-PIECE SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:DECOMPOSITION/COMBUSTION PRODUCTS MAY BE
TOXIC.

Spill Release Procedures:REMOVE SPILLAGE BY ABSORBING IN SAND OR
ABSORBENT SWEEPING COMPOUND, DISPOSE IF IN CSED CONTAINER. FLUSH
CONTAMINATED AREA WITH WATER; COLLECT WATER FOR PROR DISPOSAL.
AVOID CONTACT. CLEANUP PERSONNEL MUST WEAR PROPER PROTECTIVE
EQUIPMENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DON'T HEAT IN BULK AS DANGEROUS
DECOMPOSITION MAY OCCUR LIBERATING TOXIC FUMES. AVOID CONTACT EYES,
SKIN OR CLOTHING. DON'T BREATHE DUST.
Other Precautions:STORE IN COOL, DRY AREA IN CLOSED CONTAINTERS. WASH
THOROUGHLY AFTER HANDLING, & BEFORE EATING, DRINKING OR SMOKING.
STAY AW FROM FOOD CONTAINERS & CLOTHING. USE CLEAN CLOTHING DAILY.

Respiratory Protection:RESPIRATOR APPROVED BY NIOSH FOR ORGANIC VAPORS
FROM HOT MATERIALS.
Ventilation:WORK IN WELL VENTILATED AREAS
Protective Gloves:RECOMMENDED
Eye Protection:SAFETY GLASSES/GOGGLES
Other Protective Equipment:APPROPRIATE CLOTHING (APRONS, COVERRALLS,
GLOVES, FACE SHIELDS, GOGGLES, ETC) TO PREVENT DERMAL EXPOSURE.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
MSDS UPDATED BY DGSC-SSH TO REFLECT OSHA'S MORE STRINGENT STANDARDS FOR
MDA. USER SHOULD CONSULT LOCAL SAFETY OFFICE FOR SPECIFIC DETAILS
OF WORK PRACTICES, MEDICAL SURVEILLANCE AND HOUSEKEEPING PROCE
DURES FOR MDA EXPOSURES.

HCC:T7
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Spec Gravity:1.2
Solubility in Water:INSOLUBLE
Appearance and Odor:LIGHT YELLOW RESIN ON GLASS FABRIC.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS & BASES
Stability Condition to Avoid:AVOID CONDITIONS >250F.
Hazardous Decomposition Products:BURNING MAY PRODUCE CO, CO2, NOX &
OTHER TOXIC ORGANIC.
Conditions to Avoid Polymerization:DON'T HEAT IN BULK, DANGEROUS
EXOTHERMIC REACTION M AY OCCUR

Waste Disposal Methods:BURY OR INCINERATE IN APPROVED SITE OR FACILITY
IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.